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The CBS reduction used to be the only general solution to achieve catalytic asymmetric reduction of simple unfunctionalized ketones. This hydrogenation is highly chemoselective that ketones and aldehydes can be reduced in the presence of olefins.


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The catalytic activity of these catalysts is also very high. Depending on the substrate, the catalytic turnover TON exceeds , For its substrate generality, cleanness, and high atom economy, the Noyori hydrogenations find many applications in industrial processes.


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In Ru II -diphosphine-diamine catalytic systems, the presence of a hydrogen atom on the amine is essential and believed to play a role of stabilizing the catalyst-substrate interaction in the transition state. The hydrogenation of olefins and ketones using Ru OAc 2 binap and RuCl 2 binap dmf n requires the coordination of neighboring functional groups such as ester, amide, carboxylic acid, and alcohol.

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The CBS reduction used to be the only general solution to achieve catalytic asymmetric reduction of simple unfunctionalized ketones. This hydrogenation is highly chemoselective that ketones and aldehydes can be reduced in the presence of olefins.

The catalytic activity of these catalysts is also very high. Depending on the substrate, the catalytic turnover TON exceeds , For its substrate generality, cleanness, and high atom economy, the Noyori hydrogenations find many applications in industrial processes.